Sumanenylferrocenes and their solid state self-assembly.

نویسندگان

  • Berit Topolinski
  • Bernd M Schmidt
  • Shuhei Higashibayashi
  • Hidehiro Sakurai
  • Dieter Lentz
چکیده

The first ferrocene-fused organometallic compounds derived from the buckybowl sumanene (C21H12) are presented. Both compounds, sumanenylferrocene and 1,1'-disumanenylferrocene, have been synthesized by Negishi-type cross-coupling of iodosumanene and were studied crystallographically. Sumanenylferrocenes form unique packing motifs, which are both different from those of their corannulene congeners and sumanene itself.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 38  شماره 

صفحات  -

تاریخ انتشار 2013